Abstract
Diastereoselective 1,3-dipolar cycloadditions between C-methoxycarbonyl- N-arylnitrilimines 2 and the C N bond of enantiopure N-(1-phenylethyl)-1-arylmethanimines 3 gave diastereoisomeric 5-aryl-4,5-dihydro-1,2,4-triazolines 4 and 5. A computational description of the E→ Z isomerisation of the C N bond of unsubstituted 3a is given.
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