Abstract
Stereocontrolled total syntheses of the bridged tricyclic ketones (±)-clovan-3-one ( 5 ) and (±)- epi-clovan-3-one ( 6 ) and a facile total synthesis of the tricyclic sesquiterpene (±)-pseudoclovene-A ( 3 ) have been successfully accomplished involving participation of an aryl intramolecular cyclisation of the bromophenol 11 as a key step.
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