Abstract
Reaction of (2-ethyl-1,4-diphenyl-1-azabuta-1,3-diene)tricarbonyliron(0) 4 and (2-ethyl-1-benzyl-4-phenyl-1-azabuta-1,3-diene)tricarbonyliron(0) 7 with lithium diethylamide leads to selective formation of the corresponding endo (1-methyl-2-amino buta-1,3-diene)tricarbonyliron(0) complexes 5 and 8, respectively. In each case there is no evidence for the exo complexes 6 and 9.
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