Abstract

Sediment microbial fuel cells (SMFCs) are a typical microbial fuel cell without membranes. They are a device developed on the basis of electrochemistry and use microbes as catalysts to convert chemical energy stored in organic matter into electrical energy. This study selected a single-chamber SMFC as a research object, using online monitoring technology to accurately measure the temperature, pH, and voltage of the microbial fuel cell during the start-up process. In the process of microbial fuel cell start-up, the relationship between temperature, pH, and voltage was analysed in detail, and the correlation between them was calculated using SPSS software. The experimental results show that, at the initial stage of SMFC, the purpose of rapid growth of power production can be achieved by a large increase in temperature, but once the temperature is reduced, the power production of SMFC will soon recover to the state before the temperature change. At the beginning of SMFC, when the temperature changes drastically, pH will change the same first, and then there will be a certain degree of rebound. In the middle stage of SMFC start-up, even if the temperature will return to normal after the change, a continuous temperature drop in a short time will lead to a continuous decrease in pH value. The RBF neural network and ELM neural network were used to perform nonlinear system regression in the later stage of SMFC start-up and using the regression network to forecast part of the data. The experimental results show that the ELM neural network is more excellent in forecasting SMFC system. This article will provide important guidance for shortening start-up time and increasing power output.

Highlights

  • Microbial fuel cell (MFC) is being viewed as a potential bio-electrochemical device capable of producing energy in the form bioelectricity apart from wastewater treatment [1,2,3] which has been widely investigated in recent years

  • We chose aeration device to support Sediment microbial fuel cells (SMFCs), but we found that the effect of dissolved oxygen concentration on SMFC power generation is much less than that of temperature

  • This shows that, in the early stage of SMFC start-up, the purpose of rapid increase of electricity production can be achieved through the change of external factors, but once it loses the external field affecting it, SMFC will soon return to what it was before external factors affected it

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Summary

Introduction

Microbial fuel cell (MFC) is being viewed as a potential bio-electrochemical device capable of producing energy in the form bioelectricity apart from wastewater treatment [1,2,3] which has been widely investigated in recent years. There is no advanced monitoring method to monitor the minute changes of the parameters in the start-up process on-line This will lead to the loss of important data in the detection process and will consume a lot of manpower and material resources which will bring inconvenience to the intensive study of SMFC. Computational methods play a critical role in developing fuel cells with optimum performance in a wide range of operating conditions. Due to the lack of precise mathematical models of MFC and the above method only applicable to the condition of constant parameter and slow transformation, it is difficult to apply them to SMFC. As far as we know, there is no study on the relationship between pH, power generation and temperature during the start-up of microbial fuel cells. Due to the successful application of RBF neural network and ELM neural network in other biochemistry fields, we choose them to regress the nonlinear system in the later stage of SMFC start-up, and the regression network was used to predict the pH of that period

Data Acquisition and Processing
Results and Discussion
Conclusions
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