Abstract
Synthesis and conformational studies of α-, β-, γ-hybrid peptides containing a pyrrole amino acid (Paa, 1) and a furan amino acid (Faa, 2), namely Boc-β-Phe-Faa- d-Pro-Gly-Paa-β-HGly-Faa-OMe ( 3) and Boc-Paa-β-Phe-Faa- d-Pro-Gly-Paa-β-HGly-Faa-OMe ( 4), were carried out and they adopt β-hairpin structures stabilized via inter-strand π–π and hydrogen bonding interactions.
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