Abstract

Spectroscopic properties of Bi-doped SrB(4)O(7) glasses, sintered compounds, polycrystalline materials, and single crystals were investigated. Broadband near-infrared luminescence was realized in Bi-doped SrB(4)O(7) glasses with basicity and polycrystalline materials with non-bridging oxygens. In Bi:SrB(4)O(7) single crystals, only visible luminescence of Bi(3+) and Bi(2+) was observed, but no near-infrared. The rigid three-dimensional network of SrB(4)O(7) crystal is proved to be unfavorable for accommodation of Bi(+) ions.

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