Abstract

The specific structural features of technetium mononuclear octahedral oxo complexes have been considered. The structures of d 2-Tc(V) mono- and dioxo complexes, d 2-Tc(V) pseudodioxo compounds (Tc(V) mono-oxo complexes with an additional multiply bonded RO− ligand), and d 0-Tc(VII) trioxo compounds are analyzed.

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