Abstract

Abstract. CO2 efflux at the water–air interface is an essential component of the riverine carbon cycle. However, the lack of spatially resolved CO2 emission measurements prohibits reliable estimation of the global riverine CO2 emissions. By deploying floating chambers, seasonal changes in river water CO2 partial pressure (pCO2) and CO2 emissions from the Dong River in south China were investigated. Spatial and temporal patterns of pCO2 were mainly affected by terrestrial carbon inputs (i.e., organic and inorganic carbon) and in-stream metabolism, both of which varied due to different land cover, catchment topography, and seasonality of precipitation and temperature. Temperature-normalized gas transfer velocity (k600) in small rivers was 8.29 ± 11.29 and 4.90 ± 3.82 m d−1 for the wet season and dry season, respectively, which was nearly 70 % higher than that of large rivers (3.90 ± 5.55 m d−1 during the wet season and 2.25 ± 1.61 m d−1 during the dry season). A significant correlation was observed between k600 and flow velocity but not wind speed regardless of river size. Most of the surveyed rivers were a net CO2 source while exhibiting substantial seasonal variations. The mean CO2 flux was 300.1 and 264.2 mmol m−2 d−1 during the wet season for large and small rivers, respectively, 2-fold larger than that during the dry season. However, no significant difference in CO2 flux was observed between small and large rivers. The absence of commonly observed higher CO2 fluxes in small rivers could be associated with the depletion effect caused by abundant and consistent precipitation in this subtropical monsoon catchment.

Highlights

  • River networks act as a processor that transfers and emits the carbon entering the water, rather than just a passive pipe that transports carbon from the terrestrial ecosystem to the ocean (Cole et al, 2007; Battin et al, 2009; Drake et al, 2018)

  • The Dong River was characterized by substantial seasonal variations in hydrologic regimes (Fig. 2)

  • Stream width in the wet season was 17.0 % and 5.6 % larger than that in the dry season for small and large rivers, respectively (Table S1)

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Summary

Introduction

River networks act as a processor that transfers and emits the carbon entering the water, rather than just a passive pipe that transports carbon from the terrestrial ecosystem to the ocean (Cole et al, 2007; Battin et al, 2009; Drake et al, 2018). Understanding the role that rivers play in the global carbon cycle is still hindered by uncertainty on the flux estimate of CO2 emissions from rivers (Cole et al, 2007; Raymond et al, 2013; Sawakuchi et al, 2017; Drake et al, 2018). Global riverine CO2 emission estimates were largely based on data disproportionately focusing on temperate and boreal regions, including North

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