Abstract

Sound velocity and density measurements have been made to investigate the thermodynamic properties of the liquid Sn–Se system. The molar volume and adiabatic compressibility have been deduced as a function of temperature and composition which show large negative deviation from the ideal behaviour. The results indicate that two kinds of chemical ordering, one around 50 at.% Se and the other around 66.7 at.% Se, are formed. The latter becomes unstable with raising temperature to cause apparently complex behaviour of the thermodynamic functions.

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