Abstract
Distribution coefficients of metal acetylacetonates such as Al(acac) 3, Cr(acac) 3 and Co(acac) 3 etc., and n-alkanes in porous polystyrene gel chromatography with ten organic solvents as eluants were estimated and compared with those obtained by the batch method in two solvent systems. Solubility parameters of the metal acetylacetonates were determined. There is a relationship between the distribution coefficients and solubility parameters of solutes and solvents. Two factors (steric exclusion and partition) play important rôles in each solvent for the separation mechanisms of the present systems. The latter factor was estimated successfully from a regular solutions approximation.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
