Abstract
Hydrogen bonding heavily influences conformations, rate of reactions, and chemical equilibria. The development of a method to monitor hydrogen bonding interactions independent of polarity is challenging as both are linked. We have developed two solvatochromic dyes that detect hydrogen-bond-donating solvents. The unique solvatochromism of the triazine architecture has allowed the development of probes that monitor hydrogen-bond-donating species including water.
Highlights
We have developed two solvatochromic dyes that detect hydrogen-bond-donating solvents
The unique solvatochromism of the triazine architecture has allowed the development of probes that monitor hydrogen-bond-donating species including water
The spectral shifts of current solvatochromic dyes are influenced by both dipole interactions and hydrogen bonding.[7]
Summary
We have developed two solvatochromic dyes that detect hydrogen-bond-donating solvents. The unique solvatochromism of the triazine architecture has allowed the development of probes that monitor hydrogen-bond-donating species including water. We report the development of organic dyes, 6-(3-aminophenyl)-1,3,5-triazine-2,4-diamine (MADAT) and its acetylated analog, AMADAT, which have the ability to detect hydrogen-bond-donating solvents.
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