Abstract
The thermochemical behavior of well-established heterocyclic anticancer drug, prospidium chloride, was comparatively evaluated in water and two other non-aqueous solvents, formamide and ethylene glycol, forming the three dimensional H-bond network. Standard enthalpies and heat capacities of solution, as well as, enthalpic parameters of solute–solute pair interactions were estimated at 298 and 318 K and compared with the available values for some ionic species. A linear correlation between the energetics of ion–ion interactions and the reciprocal dielectric constant of the medium for tetraethylammonium bromide and prospidium chloride was revealed.
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