Abstract
AbstractHitherto unknown ruthenium phthalocyanine complexes with phosphane ligands – PcRu(PEt2Ph)2 (1) and PcRu(PPh3)2 (2) – soluble in common organic solvents were prepared. Two methods were used for their synthesis: 1) Reaction of phthalonitrile with [Ru2Cl3(PEt2Ph)6]Cl in n‐pentanol in the presence of 1,8‐diazabicyclo[5.4.0]undec‐7‐ene (DBU) and 2) reaction of PcRu with the corresponding phosphanes. The products 1 and 2 were characterized by their IR, UV/Vis, FD‐MS, and 1H‐NMR data.
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