Abstract
AbstractThe formation of a solid phase as the result of isothermally increasing pressure on a binary solution is analyzed from a thermodynamic point of view. Exact thermodynamic equations are presented for the case in which there are no more than one liquid and one solid phase in equilibrium for the entire range of compositions. Approximate relations incorporating the additional assumption of ideality in both solid and liquid phases are also presented. Experimental data for the system ethylene bromide‐ethylene chloride are reported and compared with predicted values. Incomplete data for the system benzene‐n‐heptane are also reported.
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