Abstract

AbstractClayey soils have the potential to swell and to shrink depending on their hydraulic and hydrological status. Thus bulk density values vary in a range of 1.0 to 2.0 g cm−3 in the case of a gleyic Vertisol, by which also other soil physical properties e.g. the pore size distribution of the bulk soil as well as of the soil aggregates are affected. Intraaggregate airfilled porosities are reduced by shrinkage and are relatively low. Thus it appeared to be difficult to determine the airfilled porosity of the aggregates below pF 1.5. For that reason and because of the influence of pore forms we were not able to get a clear relation of diffusion constant K with airfilled porosity.Regarding soil aeration status, the existence of anoxic microsites in the interior of unsaturated soil aggregates has been proved by microelectrode measurements of oxygen partial pressure and redox potential distribution in single soil aggregates. We verified restrained oxygen supply to the aggregate center as well as reduced redox potentials only for aggregates of the A horizon. There the microbial activity, measured as soil respiration as well as the source for C and N was by a factor 2 to 4 higher than in the subsurface horizons.

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