Abstract
There are two independent dodecylene disulfate molecules in the crystal of 2Na + -C 12 H 24 O 8 S 2 2- .2/3H 2 O, one with a centrosymmetric conformation, its center lying on a crystallographic center of symmetry, the second with an asymmetric conformation, which is partially disordered. The molecules form a layer structure parallel to the ab plane, the polar parts of neighbouring molecular layers connecting via coordination to the Na + ion. Additionally, there are hydrogen bonds between the water molecule and two sulfate groups.
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