Abstract

We performed an x-ray scattering study of the smectic A (SmA) ordering of the liquid crystal 8CB (octylcyanobiphenyl) confined to a control porous glass with a typical void radius R = 0.2 µm. The voids were either nontreated or covered with silane. The results reveal a strong influence of spatial restriction and surface treatment on the temperature evolution of smectic ordering. The observations are qualitatively reproduced using the Landau-Ginsburg approach.

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