Abstract
AbstractIn this paper “smart” nanocomposites comprising Stöber silica nanoparticles of two different surface polarities and a novel thermoreversible crosslinking rubber carrying self‐complementary hydrogen bonding (HB) moiety were presented. This strategy is based on the idea that the introduction of HB between silica and the modified rubber improves both the filler–rubber interaction and the mechanical properties. The resulting nanocomposites were mainly characterized using transmission electron microscopy (TEM) and dynamic mechanical analysis. It is found that the competition and symbiosis between the filler–filler, filler–rubber and rubber–rubber HB interaction, as well as the dynamic mechanical properties were controllable simply by changing the silica loading, the degree of rubber modification and the temperature. Besides, the TEM micrographs showed that the modifications of both silica nanoparticles and rubber promoted better silica dispersion in the rubber matrix. By this strategy it is evident that the Payne effect was reduced and it is possible to modify the mechanical properties of such silica filled composites in a controlled way, which could, as an example, meet the requirements for tire applications. Copyright © 2006 John Wiley & Sons, Ltd.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
