Abstract
A Mn(III)-salen-type complex with a diamagnetic [Co(III)(CN)6](3-) moiety, [Mn(III)(5-TMAM(R)-salmen)(H2O)Co(III)(CN)6]·7H2O·MeCN [1; 5-TMAM(R)-salmen = (R)-N,N'-(1-methylethylene)bis(5-trimethylammoniomethylsalicylideneiminate], was prepared. From direct-current magnetic susceptibilities, magnetization, and high-field and multifrequency electronic spin resonance measurements on powdered samples, 1 has a significant uniaxial anisotropy. Frequency-dependent alternating-current susceptibility signals were clearly observed, indicating slow magnetic relaxation. Thus, complex 1 behaves as a single-ion magnet.
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