Abstract

AbstractLinear low‐density polyethylene (LLDPE) and polypropylene (PP) were charged by sliding under a cylindrical aluminium contact. The surface charge accumulation on the polymer films was time dependent, and a function of the sliding velocity, metal contact force, and film type. The surface potential increased linearly with velocity in the range 0.33–0.75 m/s, and showed a square‐root dependence on the contact force up to 6.5 N. Thermally stimulated charge decay (TSCD) studies showed longer charge lifetimes in samples friction‐charged on one side than in corona‐charged samples. Friction charging creates deeper near‐surface traps than are normally present in the polymers. Charge stability is further imporved by simultaneously friction charging both surfaces of the films, increasing the half‐value charge decay temperature (T1/2) by 27°C and 37°C over that in corona‐charged samples (i.e., to 98°C and 120°C for LLDPE and PP, respectively). These monopolarity electrets should prove useful in charge storage devices.

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