Slagging and fouling of Zhundong coal at different air equivalence ratios in circulating fluidized bed

Abstract

Circulating fluidized bed (CFB) with low operating temperatures may become an appropriate solution to the utilization of high-Na Zhundong coal. In this paper, one kind of Zhundong coal with 3.92% Na2O in coal ash was used as fuel, and its slagging and fouling characteristics at different air equivalence ratios (ERs) were systemically investigated in 0.4t/d CFB test system to determine a better utilization scheme of Zhundong coal. The results show that ash-related problems still occurred when this high-Na coal was used in CFB, which was greatly influenced by ER. At the reducing atmosphere (ER<1.0), slagging obviously occurred in the riser at ∼940°C. Na-based species reacted with the SiO2-rich bed material to form low-melting-temperature sodium silicates (Na2O·nSiO2). The formed sodium silicates covered bed material particles and increased their stickiness. These sticky particles agglomerated and adhered onto the high-temperature metal surfaces by adhesion force or inertial force, resulting in slagging. During slagging process, Ca, Mg and Fe acted as fluxing agents. This type slagging related to the SiO2-rich bed material might be reduced or even avoided via the replacement of the bed material. At the oxidizing atmosphere (ER>1.0), fouling on tail heating surfaces at medium-low temperatures (607–735°C) was the main ash-related problem. The released AAEM-based species were transported towards low-temperature surfaces by the mechanisms of diffusion, condensation and aggregation, or thermophoresis, resulting in a layered deposition. The inner layer of deposits with micron grain sizes, which was mainly composed of Na2SO4 and K2SO4, played a key role at the initial deposition stage. Besides, two kinds of aggregated particles separately rich in alkali silicates and Ca-based species were also important for fouling.