Abstract
This paper presents a study of the Pr 4AsPh 4B assumption for the determination of thermodynamic quantities of single ions in mixed hexamethylphosphortriamide (HMPT)-water solvents. The solvation energy of Ph 4AsPh 4B is considered as a combination of electrostatic and neutral components. The neutral components are replaced by the experimental data of Pr 4Ge and Ph 4C. Based on this study, the standard free energies of transfer for K +, Rb +, Cs +, Ph 4As +, Cl −, Br −, I − and Ph 4B − are calculated from the experimental solubilities of tetraphenyl derivatives and by the use of the asymmetric Ph 4AsPh 4B assumption.
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