Abstract

Lithium battery (LiB) is widely used in electric vehicles (EVs), energy storage power stations and other fields. because of its high voltage, light weight, high energy density, good cycle performance, low self discharge rate and no memory effect, less environmental pollution and other significant advantages. However, due to the limited voltage and capacity of battery cells, battery is usually used as a battery pack composed of hundreds of single cells in parallel or series, The difference between batteries not only affect the charging and discharging capacity of batteries, but also lead to battery aging and potential safety problems. It is of great significance to study the influence of the differences between cells on the battery pack for battery grouping and battery balancing. This paper takes the coupling relationship among the initial state of charge (SOC), initial capacity and initial internal resistance into consideration, and establishes the relationship between the initial parameters. A model consists six cells connected in series is established based on the Rint equivalent circuit model, and simulations under different working conditions are conducted. The simulation results show that the consistency of the capacity of battery pack is mainly affected by the initial SOC and initial capacity. The influence of the two factors on capacity of battery pack consistency under different charging current rates is different. The initial internal resistance has little effect on capacity consistency under different charging current rates.

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