Abstract
Fractured crystalline rocks are under consideration by several countries as host formations for high-level nuclear waste repositories. The redox evolution in these host rock formations is an important issue for the stability and safety of these disposal sites. If, for example, during a glaciation/deglaciation event, oxygen-rich glacial meltwater penetrates to the depth of the planned repository, some of the engineered barriers would be adversely affected. Moreover, oxidizing conditions would increase the solubility and mobility of many radionuclides. Reactive transport simulations, which are typically used to assess the redox buffering capacity of these host rock formations, are computationally demanding, and thus, calculations for the evaluation of oxygen penetration are usually carried out over simplified geometries and the heterogeneity of the site, both physical (e.g., variability in the groundwater flow field and the kinematic porosity) and mineralogical (e.g., variability in the abundance of Fe(II)-bearing minerals), is usually represented in a simplified fashion. Here, it is shown how a recently developed numerical framework, combined with high performance computing technologies, allows the full geometrical, physical and mineralogical complexity of the site under study to be efficiently included in these types of reactive transport calculations. A synthetically generated realistic three-dimensional fractured medium is used to assess oxygen penetration patterns and their dependence on both the hydrogeological conditions and the availability of Fe(II)-bearing minerals. The results of the calculations point out the significant influence of both physical and mineralogical heterogeneity on the oxygen penetration patterns, thus highlighting the importance of a model parameterisation consistent with the site complexity.
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