Abstract
A lattice model of semiflexible linear chains (with equilibrium polydispersity) containing free volume is solved exactly on a Husimi cactus. A metastable liquid (ML) is discovered to exist only at low temperatures and is distinct (and may be disjoint) from the supercooled liquid (SCL) that exists only at high temperatures. The free volume plays a significant role in that the spinodals of the ML and SCL merge and then disappear as the free volume is reduced. The Kauzmann temperature T(K) occurs in the ML without any singularity. At T(MC)>T(K), the ML specific heat has a peak. For infinitely long polymers, the peak height diverges and the free volume vanishes at T(MC), resulting in a continuous liquid-liquid transition. Contrary to the conventional wisdom, both T(K) and T(MC) occur in the ML and not in the SCL.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
