Abstract
It is explicitly shown that the sign of the ground state g-value of IrCl6 2− was correctly calculated in earlier MCD work and that the sign recently deduced from magnetic Raman optical activity measurements agrees with this calculation. This refutesa recent suggestion by Barron et al. that a considerable body of spectroscopic assignments are thrown into doubt because this sign was incorrectly assumed in the earlier work. It is also shown that the MCD pattern in IrCl6 2− permits a correct dectuction of the sign of the ground state g-value.
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