Shock compression of cemented tungsten carbides to 100 GPa: Structure of shock waves, Hugoniot relations, and strength

Abstract

Plate impact experiments are conducted on cemented tungsten carbides (WC) with a 3.7 and 6.0 wt. % cobalt binder to better understand their dynamic, high-pressure response to 100 GPa. The measured wave profiles show propagation of steady structured waves. Standard impedance matching procedures are used to determine the Hugoniot relations in the shock velocity–particle velocity (Us−vp) and Hugoniot stress–specific volume (P−V/Vo) planes. The Hugoniot elastic limit of the samples is controlled by ductility of the Co binder and is determined to be 4.45 ± 0.29 GPa for cemented WC with 3.7 wt. % cobalt and 3.72 ± 0.24 GPa for a 6.0 wt. % cobalt binder. Both grades show a non-linear Us–vp relationship depending on whether the particle velocity is in the strength dominated or hydrodynamic regime. In the strength dominated regime, a non-linear decrease in Us is observed as vp increases from ambient to the material’s hydrodynamic limit. In the hydrodynamic regime, the Us–vp Hugoniot is linear and is determined to be Us=4.97(±0.006)+1.446(±0.018)vp km/s for WC with 3.7 wt. % Co and Us=4.93(±0.006)+1.463(±0.017)vp km/s for 6 wt. % Co. Both WC grades indicate shear-stress hardening with mean stress immediately after yield, followed by pressure softening, and then a sharp fall in stress carrying capacity as the mean stress is increased to ≈70 GPa (hydrodynamic limit) and beyond. This behavior is in contrast to pure WC ceramics, which show continued shear-stress hardening with mean stress to ≈80 GPa.