Abstract
Shake up processes accompanying core ionizations for some simple unsaturated fluorocarbon systems have been studied experimentally by ESCA. Comparison has been made of shake up intensities with those calculated theoretically within the sudden approximation using the equivalent cores concept and the INDO SCF MO formalism. The observed transitions are identified as arising from π*←π excitation accompanying core ionizations and the theoretical calculations give a good overall account of the transition probabilities.
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