Abstract
A general approach is developed for controlling the pore size and pore chemistry of integral isoporous membranes derived from the assembly of polystyrene-b-poly-4-vinyl pyridine (PS-b-P4VP) diblock copolymer. In this approach, initially, the sub-50 nm pore surface, decorated with poly-4-vinyl pyridine (P4VP) polymer brush, is coated with polyacrylic acid (PAA). PAA offers a majority of anionic and a minority of neutral acid functionalities. The neutral acid groups adhere to the P4VP segments of the pore wall through hydrogen bonding interactions and the anionic sites remain free. The availability of the anionic sites sets the stage for a layer-by-layer deposition of cationic and anionic polymers, in a sequential manner, on the pore-wall surface through a continuous flow of a dilute polyelectrolyte solution through the nanoporous membrane. In this way, multiple layers, stabilized through electrostatic interactions, can be deposited leading to a continuous decrease in the pore size and a known surface charge. Due to the known facile nature of the large area isoporous asymmetric membrane formation and modular nature of the polyelectrolyte assembly, the present approach is anticipated to yield new block copolymer membranes with tailored separation, sensing, and catalytic properties.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
