Abstract

A semiempirical model is reported to calculate diamagnetic susceptibilities of organosilicon compounds containing silicon–oxygen, silicon–sulfur and silicon–nitrogen bonds. The diamagmetic susceptibilities are considered to be contributed by the atoms, bonds, and bond–bond interactions. Diamagnetic susceptibilities are expressed in terms of parameters and have been calculated for title compounds. Semiemperical values agree with experimental values within 0.75%.

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