Abstract
Maslinic acid was obtained from olive-pressing residues, and several derivatives were formed. Rearrangements of 2-tosyloxy-derivatives of methyl maslinate made out by acetolysis. The main product of these rearrangements contained a cyclopentanic A-ring as a result of a concerted 2(3) → 4-abeo rearrangement process. Experimental and theoretical (GIAO, B3LYP/6-31G*//MM+) 13C NMR chemical shifts for 20 compounds are given.
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