Abstract
The self assembly of [Fe III(L)]Cl 2ClO 4 (L = pentadentate macrocyclic ligand) with octacyano metallates [M IV(CN) 8] 4− (M = Mo, W) leads to bimetallic cyano-bridged 2-D coordination polymers of formula [{Fe(L)} 3{M(CN) 8} 2]Cl· xH 2O with M = Mo ( 2), or W ( 3). The structure of the tungsten analogue has been established by single crystal X-ray diffraction. The magnetic properties for both Mo and W derivative are reported.
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