Abstract
ABSTRACTA new cadmium(II) coordination polymer, [Cd(ntdc)(dps)·H2O]n, was synthesized using 3-nitro-thiophene-2,5-dicarboxylic acid (H2ntdc) and 4,4´-dipyridylsulfide (dps) as organic linkers. In the complex, adjacent Cd2+ ions are linked by ntdc2− anions adopting a new coordination mode to form a one-dimensional (1D) [Cd(ntdc)]n chain. Then dps ligands further expand the 1D chain into a corrugated two-dimensional (2D) layer network by linking neighboring Cd2+ ions. Topologically, the 2D network can be rationalized to a 3,5-connected 3,5L2 topology. Moreover, solid state properties such as thermogravimetric analysis and photoluminescent property were also investigated.
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