Secondary Organic Aerosol from Biomass Burning Phenolic Compounds and Nitrate Radicals can be Highly Viscous over a Wide Relative Humidity Range.

Abstract

Biomass burning events, including wildfires, can emit large amounts of phenolic compounds such as guaiacol. These phenolic compounds can undergo oxidation by nitrate radicals (NO3) to form secondary organic aerosol (SOA). Viscosity and hygroscopicity are key properties that affect SOA's role in atmospheric chemistry, air quality, climate and public health. However, these properties have not been quantified for SOA formed from the reaction of phenolic compounds with NO3. We used the poke-flow technique and a quartz crystal microbalance (QCM) to measure the viscosity and hygroscopicity of SOA particles generated from the reaction of NO3 with guaiacol, termed guaiacol-NO3 SOA. The viscosity of this SOA is extremely high (≳5 × 107 Pa s) at RH ≲ 70% and drastically higher than other SOA types previously investigated with the poke-flow technique at RH ≳ 40%. The high viscosity for guaiacol-NO3 SOA can be attributed, at least in part, to the low hygroscopicity measured via the QCM. From the viscosity results, we calculated the mixing times of organic molecules within guaiacol-NO3 SOA. The results suggest that mixing times within this type of SOA exceed 1 h for most tropospheric conditions, with possible implications for predicting the size, mass, and long-range transport of pollutants in phenolic SOA.