Secondary compositional zoning of garnet from the high-grade metamorphic Gföhl Unit, Moldanubian Zone: constraints on relative cation diffusivities and geodynamic processes

Mafic–ultramafic lenses embedded in felsic granulites of the Gföhl Unit, Moldanubian Zone, are considered to be mantle fragments incorporated into mid-crustal levels of the Variscan orogenic crust. We investigated a several 100 m sized mafic lens mainly formed by garnet pyroxenite. The primary mineral assemblage comprises calcium-rich garnet (XGrs = 0.4), kyanite, and sodium-rich clinopyroxene (XNa_M2 = 0.29) (± quartz), which indicates pressures above 1.8 GPa and temperatures around 1000 °C. Towards the margins of the mafic lens, the garnet pyroxenites were increasingly overprinted at lower pressures leading to the destabilization of kyanite, Na-rich clinopyroxene, and garnet. A first decompression phase is represented by garnet-hosted sapphirine–spinel–plagioclase symplectites supposedly replacing kyanite and clinopyroxene. A second stage is evident from the partial resorption of garnet by plagioclase and clinopyroxene in the form of a peculiar corrosion tubes penetrating the garnet in a worm-like fashion. Finally, the third stage decompression assemblage is represented by plagioclase–orthopyroxene–spinel symplectites partially replacing garnet. In all cases, garnet shows pronounced secondary compositional zoning towards the decompression products. The secondary zoning is qualitatively similar for the sapphirine–spinel–plagioclase symplectites and the plagioclase–clinopyroxene corrosion tubes and is characterized by a strong decrease of the Grs content accompanied by an increase of the Alm and Prp contents towards the decompression products. For the sapphirine–spinel–plagioclase symplectite, the garnet composition changes from Alm14Prp42Grs44 in the pristine garnet to Alm22Prp63Grs15 at the interface to the symplectite. The compositional change towards the corrosion tubes is from Alm19Prp40Grs41 to Alm30Prp54Grs16. The secondary zoning towards the plagioclase–orthopyroxene–spinel symplectites is characterized by an increase of XAlm from 0.19 to 0.27 and a concomitant decrease of XPrp from 0.55 to 0.49 at constant XGrs of 0.25. In all cases, the compositional changes are gradual suggesting diffusion-mediated re-equilibration of the garnet at decreasing pressures. Time scales for the duration of decompression were estimated by fitting a multicomponent diffusion model to the observed compositional patterns. Depending on the choice of the diffusion coefficients, the time scales vary from several hundreds to hundred thousands of years, whereby the earliest decompression features yield time scales that are five times longer than those obtained from the corrosion tubes and about ten times longer than those obtained from the plagioclase–orthopyroxene–spinel symplectites. These timescales reflect the duration from the onset of the different decompression-induced mineral reactions to the time when the rocks cooled below about 700 °C and the composition patterns of the garnet were effectively frozen. The longest timescales obtained from the early decompression reactions are on the order of 100,000 years and the shortest timescales obtained from the late-stage symplectites are on the order of 1,000 years. Considering the regional metamorphic setting of the Moldanubian Zone, such timescales are remarkably short and suggest rapid transport of the mafic–ultramafic lithologies from mantle depths to the mid-crustal level. Concomitant incorporation into a dominantly felsic environment led to immediate cooling.

Garnet‐bearing ultramafic rocks (GBUR) enclosed in granulite or high‐grade gneiss are rare, yet typical constituents of alpine‐type collisional orogens. The Bohemian Massif of the European Variscides is exceptional for the occurrence of a large variety of mantle‐derived rocks, including GBUR (garnet peridotite and garnet pyroxenite). GBUR occur in several metamorphic units belonging to both the Saxothuringian and the Moldanubian zones of the Bohemian Massif. The northernmost outcrops of GBUR in the Bohemian Massif are situated in the Saxonian Granulitgebirge Core Complex in the Saxothuringian zone and are the subject of this study. Thermobarometric results and exsolution textures imply that the Granulitgebirge GBUR belong to the ultra high temperature group of peridotites. They experienced a decompression‐cooling path being constrained by the following four stages: (i) ∼1300–1400 °C and 32 kbar, (ii) 1000–1050 °C and 26 kbar, (iii) 900–940 °C and 22 kbar, and (iv) 860 °C and 12–13 kbar. Occasional layers of garnet pyroxenite within GBUR lenses are interpreted as high pressure cumulates that crystallized at 32–36 kbar by cooling below 1400 °C. The GBUR were most probably derived from upwelling asthenosphere and came in contact with crustal granulite at ∼60 km depth. Slab break‐off is suggested here as the most probable cause for: (i) asthenosphere upwelling and cooling of the latter as well as (ii) ultra high temperature granulite facies metamorphism of the crustal host rocks. The Granulitgebirge‐type peridotite is very similar to the Mohelno‐type peridotite from the Gföhl unit, Moldanubian zone, in the southern part of the Bohemian Massif. In contrast, peridotite from the adjacent Erzgebirge (also within the Saxothuringian zone) is derived from the subcontinental mantle and much resembles the Nove Dvory‐type peridotite from the Gföhl unit (Moldanubian zone). The fact that the Saxothuringian and Moldanubian zones host the same types of mantle rocks (asthenospheric and lithospheric) of the same metamorphic ages suggests that the classic distinction into the Saxothuringian and Moldanubian zones cannot be supported, at least as far as high‐grade units hosting GBUR are concerned.

12 - Distribution and Geological Position of High-/Ultrahigh-Pressure Units Within the European Variscan Belt: A Review

Preface

High-pressure granulites of the Podolsko complex, Bohemian Massif: An example of crustal rocks that were subducted to mantle depths and survived a pervasive mid-crustal high-temperature overprint

Two-pyroxene syenitoids from the Moldanubian Zone of the Bohemian Massif: Peculiar magmas derived from a strongly enriched lithospheric mantle source

Terrane boundaries in the Bohemian Massif: Result of large-scale Variscan shearing

The orogenic development after the continental collision between Laurussia and Gondwana, led to two contrasting associations of mantle-derived magmatic rocks on the territory of the Bohemian Massif: (i) a 340–310 Ma lamprophyre-lamproite orogenic association; and (ii) a 300–275 Ma lamprophyre association of anorogenic affinity. Major types of potassic mantle-derived magmatic rocks recognized in the orogenic and anorogenic associations include: (i) calc-alkaline to alkaline lamprophyres; (ii) alkaline ‘orthopyroxene minettes’ and geochemically related rocks grouped here under the new term lampyrite; and (iii) peralkaline lamproites. These three types significantly differ with respect to mineral, whole-rock and Sr–Nd–Pb–Li isotope composition and spatial distribution. The calc-alkaline lamprophyres occur throughout the entire Saxo-Thuringian and Moldanubian zones, whereas the different types of malte-derived potassic rocks are spatially restricted to particular zones. Rocks of the Carboniferous lamprophyre-lamproite orogenic association are characterized by variable negative εNd(i) and variably radiogenic Sr(i), whereas the rocks of the Permian lamprophyre association of anorogenic affinity are characterized by positive εNd(i) and relatively young depleted-mantle Nd-model ages reflecting increasing input from upwelling asthenospheric mantle. The small variation in the Pb isotopic composition of post-collisional potassic mantle-derived magmatic rocks (of both the orogenic and anorogenic series) implies that the Pb budget of the mantle beneath the Bohemian Massif is dominated by the same crust-derived material, which itself may include material derived from several sources. The source rocks of ‘orthopyroxene minettes’ are characterized by isotopically light (‘eclogitic’) Li and strongly radiogenic (crustal) Sr and may have been metasomatized by high-pressure fluids along the edge of a subduction zone. In contrast, the strongly Al2O3 and CaO depleted mantle source of the lamproites is characterized by isotopically heavy Li and high SiO2 and extreme K2O contents. This mantle source may have been metasomatized predominantly by melts. The mantle source of the lamprophyres may have undergone metasomatism by both fluids and melts.

Highly evolved miaskitic syenites deciphering the origin and nature of enriched mantle source of ultrapotassic magmatism in the Variscan orogenic root (Bohemian Massif, Moldanubian Zone)

High-temperature, high-pressure eclogite and garnet pyroxenite occur as lenses in garnet peridotite bodies of the Gfohl nappe in the Bohemian Massif. The high-pressure assemblages formed in the mantle and are important for allowing investigations of mantle compositions and processes. Eclogite is distinguished from garnet pyroxenite on the basis of elemental composition, with mg number 0.75 wt.%, Cr2O3 < 0.15 wt.% and Ni < 400 ppm. Considerable scatter in two-element variation diagrams and the common modal layering of some eclogite bodies indicate the importance of crystal accumulation in eclogite and garnet pyroxenite petrogenesis. A wide range in isotopic composition of clinopyroxene separates [eNd, +5.4 to −6.0; (87Sr/86Sr)i, 0.70314–0.71445; δ18OSMOW, 3.8–5.8%o] requires that subducted oceanic crust is a component in some melts from which eclogite and garnet pyroxenite crystallized. Variscan Sm-Nd ages were obtained for garnet-clinopyroxene pairs from Dobesovice eclogite (338 Ma), Uhrov eclogite (344 Ma) and Nove Dvory garnet pyroxenite (343 Ma). Gfohl eclogite and garnet pyroxenite formed by high-pressure crystal accumulation (±trapped melt) from transient melts in the lithosphere, and the source of such melts was subducted, hydrothermally altered oceanic crust, including subducted sediments. Much of the chemical variation in the eclogites can be explained by simple fractional crystallization, whereas variation in the pyroxenites indicates fractional crystallization accompanied by some assimilation of the peridotite host.

The Gföhl nappe, the uppermost structural unit in the Moldanubian Zone of the Variscan Bohemian Massif, contains a distinctive association of HP crustal granulite (900-1000°C, 15-18 kbar) and UHP mantle garnet peridotite (875-1150°C, 33-60 kbar). Ultrahigh-pressure (UHP) garnet peridotite is host to layers and lenses of garnet pyroxenite and eclogite, which formed by high-pressure crystal accumulation of garnet and pyroxene (± trapped melt) from transient melts in subcontinental lithosphere. The source of such melts was subducted, hydrothermally altered oceanic crust. New analyses of garnet websterite, orthopyroxene eclogite, and kyanite eclogite yield temperatures of 840-950°C and pressures of 34-43 kbar, comparable to those of enclosing peridotite, although kyanite eclogite at one locality (Ührov) yields significantly different values of 1030-1200°C and 17-22 kbar. Most petrological and geochemical features of the Gföhl crustal and mantle association can be explained in terms of Devonian (Emsian to Famennian) convergence and subduction of Moldanubia beneath Tepla-Barrandia, culminating in Early Carboniferous (Tournaisian) continental collision. However, this tectonic scenario fails to account for a pressure gap of ∼20 kbar between HP granulite and UHP peridotite-pyroxenite-eclogite, which remains problematic.

Basin analysis, quantitative methods, volume 2: Ian Lerche Academic Press; 1990; ISBN 012 444 1734; 570 pp. Price: £81.00

Eclogite facies rocks of the Monotonous unit, clue to Variscan suture in the Moldanubian Zone (Bohemian Massif)

Metacarbonates of the Moldanubian Zone (Bohemian Massif, Czech Republic) were studied to obtain qualitative and quantitative mineralogical-petrographic as well as stable isotopic data for the purpose of stone provenance studies, potentially applicable in material research studies of cultural heritage artefacts. Twenty-six samples from twelve different historical quarries, as well as two samples from historical artefacts, were analysed by both mineralogical-petrographic and geochemical methods including: polarizing microscopy, cathodoluminescence, scanning electron microscopy with microanalysis, petrographic image analysis, powder X-ray diffraction, and isotope ratio mass spectrometry. The petrographic characteristics allowed for the discrimination of groups of (1) calcitic marbles, (2) dolomitic marbles, and (3) carbonate–silicate rocks. These groups exhibit characteristic features such as (1) the presence/abundance of major rock-forming minerals, (2) grain geometric characteristics (specifically, mean carbonate grain size and index of grain size homogeneity), and (3) the presence of specific accessory phases. The content of non-carbonate minerals, some rock fabric parameters, as well as the carbon and oxygen isotope data exhibited significant variability, even within a single quarry in the case of some impure marbles and carbonate–silicate rocks. Although the carbon and oxygen isotopic ranges displayed overlaps among the quarries studied, the isotopic signatures throughout the Moldanubian Zone allowed for discrimination of a group of white calcitic marbles with high carbon and oxygen depletion, as well as white dolomite–calcitic marble with higher carbon isotope values when compared with other marble resources of the Bohemian Massif. A combination of the isotopic signature with detailed mineralogical-petrographic characteristics seems to provide sufficient information for discrimination of the Moldanubian marbles from one another. The provenance of the Vrchotovy Janovice artefact is very probably from the Rabi quarry, among the Moldanubian marbles. The provenance of the artefact from the Prague Klementinum was not definitively assigned; however, the Nehodiv quarry was considered its probable source locality.

Recent petrological studies on high‐pressure (HP)–ultrahigh‐pressure (UHP) metamorphic rocks in the Moldanubian Zone, mainly utilizing compositional zoning and solid phase inclusions in garnet from a variety of lithologies, have established a prograde history involving subduction and subsequent granulite facies metamorphism during the Variscan Orogeny. Two temporally separate metamorphic events are developed rather than a single P–T loop for the HP–UHP metamorphism and amphibolite–granulite facies overprint in the Moldanubian Zone. Here further evidence is presented that the granulite facies metamorphism occurred after the HP–UHP rocks had been exhumed to different levels of the middle or upper crust. A medium‐temperature eclogite that is part of a series of tectonic blocks and lenses within migmatites contains a well‐preserved eclogite facies assemblage with omphacite and prograde zoned garnet. Omphacite is partly replaced by a symplectite of diopside + plagioclase + amphibole. Garnet and omphacite equilibria and pseudosection calculations indicate that the HP metamorphism occurred at relatively low temperature conditions of ~600 °C at 2.0–2.2 GPa. The striking feature of the rocks is the presence of garnet porphyroblasts with veins filled by a granulite facies assemblage of olivine, spinel and Ca‐rich plagioclase. These minerals occur as a symplectite forming symmetric zones, a central zone rich in olivine that is separated from the host garnet by two marginal zones consisting of plagioclase with small amounts of spinel. Mineral textures in the veins show that they were first filled mostly by calcic amphibole, which was later transformed into granulite facies assemblages. The olivine‐spinel equilibria and pseudosection calculations indicate temperatures of ~850–900 °C at pressure below 0.7 GPa. The preservation of eclogite facies assemblages implies that the granulite facies overprint was a short‐lived process. The new results point to a geodynamic model where HP–UHP rocks are exhumed to amphibolite facies conditions with subsequent granulite facies heating by mantle‐derived magma in the middle and upper crust.