Seamless Hourly Estimation of Negative Air Ion Concentrations: Integrating Hybrid Stacked Machine Learning Models With Kriging Spatiotemporal Augmentation

Abstract

AbstractNegative Air Ions (NAIs), essential for environmental and human health, facilitate air purification and offer antimicrobial benefits. Our study achieves hourly estimations of NAIs using a machine learning framework, developed from a multi‐layer selection pipeline of over 200 variables, to identify the key determinants critical for adapting to high‐resolution NAIs dynamics. Addressing site sparsity and NAIs volatility, we introduced a hybrid stacking incorporating pseudo sites generated from Kriging Spatiotemporal Augmentation (KSTA) to mitigate spatial overfitting. Our approach, validated in Zhejiang, China, demonstrates exceptional accuracy, achieving R2 values of 0.90 (sample‐based), 0.85 (temporal‐based), and 0.79 (site‐based). This work not only sheds light on NAIs behavior in relation to diurnal shifts, land use, and environmental events, but also integrates a health grading system, enhancing public health strategies through precise air quality assessment.