Abstract
Scandium(III) triflate-catalyzed allylation of carbonyl compounds with tetraalylgermane proceeded readily in aqueous nitromethane to afford homoallyl alcohols in excellent to good yields. The presence of H 2O is indispensable for the allylation of aldehydes to proceed smoothly. Aldehydes were allylated highly chemoselectively in the presence of ketone moieties.
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