Abstract
The title complex salt, (C12H16NO2)[PdCl2(C12H14NO2)], is of interest with respect to organic and organometallic catalysis. The compound crystallizes as very small orange–red irregular prisms and the asymmetric unit contains three crystallographically distinct cation–anion pairs. The coordination geometry about the palladium atoms is square-planar with the chloride ligands cis to one another. The structure displays N—H⋯Cl and O—H⋯O hydrogen bonding such that the N—H⋯Cl hydrogen bonds align the cation–anion pairs in a linear fashion along [001], with the O—H⋯O hydrogen bonds connecting these linear strands along [100] and [010].
Highlights
The compound crystallizes as very small orange–red irregular prisms and the asymmetric unit contains three crystallographically distinct cation–anion pairs
Symmetry codes: (i) x, y−1, z; (ii) x, y+1, z; (iii) x+1, y+1, z; (iv) x+1, y, z−1; (v) x, y, z+1
Summary
N—H Cl hydrogen bonds align the cation–anion pairs in a linear fashion along [001], with the O—H O hydrogen bonds connecting these linear strands along [100] and [010]
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
