Abstract

Hydroxypropyl-cellulose (HPC), a derivative of naturally abundant cellulose, can self-assemble into helical nanostructures that lead to striking colouration from Bragg reflections. The helical periodicity is very sensitive to pressure, rendering HPC a responsive photonic material. Recent advances in elucidating these HPC mechano-chromic properties have so-far delivered few real-world applications, which require both up-scaling fabrication and digital translation of their colour changes. Here we present roll-to-roll manufactured metre-scale HPC laminates using continuous coating and encapsulation. We quantify the pressure response of the encapsulated HPC using optical analyses of the pressure-induced hue change as perceived by the human eye and digital imaging. Finally, we show the ability to capture real-time pressure distributions and temporal evolution of a human foot-print on our HPC laminates. This is the first demonstration of a large area and cost-effective method for fabricating HPC stimuli-responsive photonic films, which can generate pressure maps that can be read out with standard cameras.

Highlights

  • Hydroxypropyl-cellulose (HPC), a derivative of naturally abundant cellulose, can selfassemble into helical nanostructures that lead to striking colouration from Bragg reflections

  • The cellulose derivative hydroxypropyl-cellulose (HPC) is a promising self-assembling photonic material with the advantages of being low-cost, non-toxic, water-soluble and having been used widely by the medical and food industries as an emulsifier and thickener[30,31]

  • In addition to large area continuous coatings, we believe an important step towards the commercial adoption of these materials is an accessible method to translate the mechano-chromic colour changes of the films into a pressure map

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Summary

Introduction

Hydroxypropyl-cellulose (HPC), a derivative of naturally abundant cellulose, can selfassemble into helical nanostructures that lead to striking colouration from Bragg reflections. We show that low-pressure R2R slot-die coating and lamination allows for the continuous self-assembly of HPC into mechano-chromic packaged films. In addition to large area continuous coatings, we believe an important step towards the commercial adoption of these materials is an accessible method to translate the mechano-chromic colour changes of the films into a pressure map.

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