Abstract
AbstractThe phase‐separation behavior of high‐density polyethylene (HDPE)/diluent blends was monitored with a torque variation method (TVM). The torque variation of the molten blends was recorded with a rheometer. It was verified that TVM is an efficient way to detect the thermal phase behavior of a polymer–diluent system. Subsequently, polyethylene hollow‐fiber membranes were fabricated from HDPE/dodecanol/soybean oil blends via thermally induced phase separation. Hollow‐fiber membranes with a dense outer surface of spherulites were observed. Furthermore, the effects of the spinning temperature, air‐gap distance, cold drawing, and HDPE content on the morphology and gas permeability of the resultant membranes were examined. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010
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