Abstract

Three-dimensional Rh particle catalysts were prepared by heteroepitaxial growth on α-Al 2O 3 (0001), NaCl (001) and KCl (001) substrates. During the deposition, the particle structure and orientation were characterised by Reflection High Energy Electron Diffraction (RHEED). It was shown that at sufficiently high temperatures the Rh particles conserve the symmetry of the susubstrate (hexagonal in the case of α-Al 2O 3 (0001) and cubic for (001) NaCl and (001) KCl substrates). At lower temperatures the layers are disordered or partially disordered.

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