Abstract

This paper demonstrates an RF thermal plasma pyrolysis reaction apparatus that achieves 89 wt.% reaction conversion yield with no tar content. The demonstrated experimental apparatus consists of a 1100 W RFVII Inc. (104 Church St, Newfield, NJ 08344, United States) @ 13.56 MHz RF thermal plasma generator, a Navio matching network, intelligent feedback controller, and an 8-turn copper RF-ICP torch embedded in a 12 L thermochemical reactor. The intelligent feedback controller optimizes the thermal performance based on feedback signals from three online gas analyzers: CO, CO2 and NOx. The feedback controller output signal controls the RF thermal plasma torch current that provides real-time temperature control. The proposed reaction system achieves precise temperature profiles for both pyrolysis and gasification as well as increases end-product yield and eliminates undesired products such as tar and char. The identified hydrocarbon liquid mixture is 90 wt.% gasoline and 10 wt.%. diesel. The 8-turn RF-ICP thermal plasma torch has an average heating rate of +35 °C/min and a maximum operating temperature of 2000 °C and is able to sustain stable flame for more than 30 min. The reaction operating parameters are (550–990 °C τ = 30 min for pyrolysis and (1300 °C τ = 1 sec) for the gasification process. The identified hydrocarbon liquid products are 90 wt.% of a n-butyl-benzene (C6H5C4H9) and oluene (C7H8) mixture with less than 10 wt.% decane diesel fuel (C10 H22). Comsol simulation is used to assess the RF-ICP thermal plasma torch’s thermal performance.

Highlights

  • Global municipal solid waste (MSW) generation exceeds 2.01 billion tons per annum while untreated global solid waste depositions are expected to reach 27 billion tons by 2050 [1,2]

  • Non-hazardous annual solid waste generation is estimated at 25 million metric tons per annum and is considered a main source of greenhouse gas emissions in the waste management sector [3,4]

  • Thermal plasma is under a local partial thermodynamic equilibrium (LTE); Plasma is considered a conductive fluid mixture and is modelled using magnetohydrodynamics (MHD) equations; The thermal plasma jet is axisymmetric, optically thin, and at a local thermodynamic equilibrium; The gaseous velocity is constant at laminar flow with no tangential components; The displacement current and electrostatic fields are neglected

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Summary

Introduction

Global municipal solid waste (MSW) generation exceeds 2.01 billion tons per annum while untreated global solid waste depositions are expected to reach 27 billion tons by 2050 [1,2]. In. Canada, non-hazardous annual solid waste generation is estimated at 25 million metric tons per annum and is considered a main source of greenhouse gas emissions in the waste management sector [3,4]. Processes 2020, 8, 281 for solid waste deposits with negligible greenhouse gas emissions. Processes 2019, 7, x FOR PEER REVIEW are only seven municipal incineration sites in Canada processing 763,000 tons/annum of MSW using. There are only seven municipal and incineration sitesheaters in Canada processing. The unsorted of MSW using conventional thermal methods such as furnaces and fired gas heaters [8,9]. 40 MJ/kghas [8,10]

Thermochemical
Characterization of Thermal Plasma Jets
Tar Tolerance Levels in Pyrolysis Reactors
DC and RF Thermal Plasma Generation Systems
DC Transferred and Non-Transferred Arcs
RF Thermal Plasma Conservation Equations and Process Control Algorithms
End-Product Gas Yield Control Algorithms
RF Thermal Plasma Simulation
RF Torch Assumptions
Equipment
Reaction
Experimental Analysis and Results
13. RF thermal plasma pyrolysis
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