Abstract
Why Fe⊕‐complexed n‐propylamine decomposes into H2, NH3, ethylene and propylene in the mass spectrometer cannot be explained in terms of current concepts. Tandem MS experiments with deuteriated n‐propylamine enable an explanation: H2, NH3 and propylene could be formed via an n‐propyl‐Fe⊕‐NH2 complex, which rearranges to the propene complex. For the formation of ethylene, a route via a four‐membered FeNC2 complex and its conversion into an ethylene complex is possible.
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