Abstract

Current knowledge about black carbon (BC) emission estimates, state-of-the-art measurement methods, near-surface BC concentrations ([BC]), and mixing ratios in snow is consolidated for the Arctic. Since no direct method exists to measure [BC], results from modern indirect methods differ among devices. Pan-Arctic wide [BC] and changes are hard to access; monitoring often ends once national ambient air quality standards are met. Few remote sites have long records. Past measurements showed distinct differences among the various Arctic climate regions. Past and own observations in communities permit qualitative discussion of the diurnal course, response to weather, season, or different emission situations like weekdays and weekends at a given site and/or among sites. Comparison of data from collocated aethalometer indicated more similar accuracy than found in mid- and low-latitudes despite of much lower ambient temperatures and [BC]. Snow samples give an incomplete glimpse at the removal and input into ecosystems.

Highlights

  • In this Millennium, black carbon (BC) in the Arctic has gained huge public interest [1]

  • That permits comparison of BC measurements by identical aethalometer at different sites. This factor gives how much greater the attenuation coefficient is when compared to the light absorption coefficient of the co-located filter-based absorption photometer that had been corrected for loading and scattering artifacts

  • Meteorological and oceanic conditions influence BC emissions, [BC], aerosol formation, accumulation, aging and removal. Since these conditions occur with regularity in a region, we conclude that [BC] mitigation measures in response to the anticipated increase of Arctic shipping have to be assessed with air quality models, which need spatial and temporal emission data as input

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Summary

Introduction

In this Millennium, black carbon (BC) in the Arctic has gained huge public interest [1]. Upon emission, BC particles undergo complex processes with co-emitted OC, toxic semi-volatile organics, inorganic salts from both nitrogen dioxide (NO2) and sulfur dioxide (SO2), as well as atmospheric water. These species may deposit on hygroscopic carbonaceous particles; other aerosol components can join BC during particle growth [6]. Emission inventories and measurements of concentration baselines, are pre-requisites to assess impacts from anticipated increases in Arctic shipping on human and ecosystem health as well as subsistence lifestyle. We consider the region north of 59.9N as “Arctic”

Black Carbon Emissions
Arctic Emission Sources
Emission Inventories
Measuring Near-Surface Black Carbon Concentrations
Aethalometer
Thermal Techniques
Acoustic Detection Method
Instrument Comparison and Cross-Calibration
Normalization of Data from Various Sites
Black Carbon in the Near-Surface Atmosphere
Black Carbon in Snow
Findings
Conclusions and Recommendations
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