Abstract
This study reports the first structural elucidation of β-diketiminate anions (BDI-), known for strong coordination, in their unbound form within caesium complexes. β-Diketiminate caesium salts (BDICs) were synthesised, and upon the addition of Lewis donor ligands, free BDI- anions and donor-solvated Cs+ cations were observed. Notably, the liberated BDI- anions exhibited an unprecedented dynamic cisoid-transoid exchange in solution.
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