Abstract
This work is in response to the “Comment on ’Formation of silyl metal hydride, HMnSiH3 and silylidyne, H3ReSiH in the activation of silane by manganese and rhenium atoms’”. The experimental results indicate that the assignment of the absorptions at 1804.5 cm−1 to the Re-H stretching vibration of H3ReSiH is more appropriate than to H3Re(μ-H)Si, since the Re-Hb (Hb = bridging hydrogen) stretching vibration, which is predicted to have considerable IR intensity, was not observed in the experiments.
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