Abstract
We have performed diffusion quantum Monte Carlo simulations of Li clusters showing that resonating-valence-bond (RVB) pairing correlations between electrons provide a substantial contribution to the cohesive energy. The RVB effects are identified in terms of electron transfers from $s$-like to $p$-like character, constituting a possible explanation for the breakdown of the Fermi-liquid picture observed in recent high-resolution Compton scattering experiments for bulk Li.
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