Abstract

The resonance-enhanced multiphoton ionization (REMPI) spectrum of NO has been obtained in the range of 420-480nm with a Nd.YAG pumped optical parametric generator and amplifier. The spectral lines can be attributed to NO X2?(v'' = 0,1) ? A2?(v ' = 0,1) and X2?(v'= 0) ?* E2?(v ' = 0~4)transitions. In this wavelength range, NO molecules are ionized via the resonant intermediate states A2?+ or E2? and by (2+2) or (3+1) REMPI process. The dependence of ion signals on laser intensity is in good agreement with these results.

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