Abstract
Low-temperature resonance Raman spectroscopy has been used to investigate the nickel coordination geometry in the [Ni(SPh) 4 ] 2- anion in solution, Ni(II)-substituted rubredoxins from Desulfovibrio and Pyrococcus furiosus and Ni(II)-substituted desulforedoxin from D. gigas. Ni-S vibrational modes have been assigned on the basis of 58 Ni/ 60 Ni isotope shirts, polarization studies, and comparison with structurally characterized tetrathiolate Ni(II) complexes
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
