Abstract
The thermal performance of high-energy hydrazine nitrate complexes [Zn(N2H4)2(NO3)2]n, [Cd(N2H4)2(NO3)2]n, [Co(N2H4)3](NO3)2 and [Ni(N2H4)3](NO3)2 (signed as ZnHN, CdHN, CoHN and NiHN) was researched systematically. The thermal behavior, kinetics, thermal safety and storage life of them were investigated by the DSC, TG and dynamic pressure measuring thermal analysis method. The thermal decomposition of CdHN and ZnHN with NO3 − as ligand is more complicated than CoHN and NiHN with NO3 − as counterion indicating that similar structures have some influence on the thermal properties, but there is no necessary relationship. DSC curves and TG mass-loss stages of CdHN and ZnHN are similar but their thermal decomposition mechanism is quite different.
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